刘波研究员----高分子物理与化学国家重点实验室

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刘波研究员

文章来源：发布时间：2020-10-22

	刘波　研究员

	高分子化学与物理


	合成楼219室

	电话：0431 85262774
	传真：0431 85262774
	Email：liubo@ciac.ac.cn

教育和工作经历

2013.03- 中国科学院长春应用化学研究所，副研究员、研究员
2010.09-2013.02 法国雷恩一大博士后
2004.09-2010.03 长春应用化学研究所，高分子化学与物理专业，理学博士
2000.09-2004.07 东北林业大学，高分子化学专业，工学学士

学术兼职

主要荣誉

2020年吉林省自然科学奖一等奖（排名第二）
2018年获得“中国橡胶科技创新奖”
2011.09-2013.02 “Marie Curie International Incoming Fellowships”（欧盟玛丽居里奖学金）

研究兴趣

烯烃序列可控聚合、CO2高值化利用、新型橡胶的应用研究

研究资助

主持国家自然基金面上项目2项，国际合作1项，企业合作项目3项

研究领域和现状

一、“协助活性中心识别”裁剪聚苯乙烯序列创制出高击穿电压的绝缘材料
发展外加Lewis碱调节苯乙烯与活性中心配位能力的“协助活性中心识别”策略。以该策略为准则，通过增大中心金属周围空间位阻、削弱中心金属Lewis酸性，实现了乙烯/苯乙烯共聚时对聚苯乙烯序列的可控裁剪，制备出击穿电压（395 kV/mm）高于广泛使用的进口低密度聚乙烯（284.2 kV/mm）的绝缘材料

二、“链末端自识别”调节共轭二烯不同选择性聚合控制机制创造高端橡胶
以“链末端自识别”策略为准则，调控链末端反咬强弱，突破了同一催化剂对丁二烯、异戊二烯聚合选择性控制机制相似的传统观念，创造性地将耐磨的顺-1,4聚丁二烯橡胶和抗湿滑的3,4-聚异戊二烯弹性体可控地融合到一条分子链上，创制出综合性能比目前轿车胎广泛采用的丁苯橡胶优异的新概念“集成橡胶”；调控链末端异构化程度，解决了近六十年来乙烯/丁二烯顺1,4聚合机理不同难以无规共聚合的难题，实现橡胶、塑料分子水平的融合，创制出高强、耐低温的橡塑合金

三、创建 “区域选择性链穿梭”聚合、“开关”聚合，一锅法制备多嵌段聚合物
构筑“区域选择性链穿梭”聚合方法，利用异戊二烯一种单体制备出玻璃化温度可调的1,4-聚异戊二烯和3,4-聚异戊二烯多嵌段橡胶；拓展“链穿梭”聚合适用单体范围，利用难以共聚的乙烯、苯乙烯制备出多嵌段共聚物。首次发现了可完美触发“开关”的元素—Lewis酸碱作用，创建了苯乙烯/异戊二烯“开关”共聚合，制备出微相结构可调的苯乙烯/共轭二烯多嵌段橡塑合金

主要代表性论文

1. Liu Na;^⊥Liu Doudou;^⊥Liu Bo;* Zhang Hao;* Cui, Dongmei; “Stereoselective polymerization of rac-lactide catalyzed by zwitterionic calcium complexes”, Polym. Chem., 2021, 12, 1518-1525.

2. Wu Yi;^⊥Wang Zichuan;^⊥Liu Dongtao; Liu Bo;* Cui Dongmei; “Highly Syndioselective Coordination (Co)Polymerization of para-Chlorostyrene” Macromolecules, 2020, 53, 8333-8339.

3. Zhu Yuanwei; Fan Yongkang; Li Shengtao;* Wei Peng; Li Dongfan; Liu Bo;* Cui Dongmei; Zhang Zhicheng; Li Guochang; Nie Yongjie; Lu Guanghao;* “Soluble poly(4-fluorostyrene): a high-performance dielectric electret for organic transistors and memories” Mater. Horiz., 2020, 7, 1861-1871.

4. Lin Fei; Liu Zhaohe; Wang Meiyan; Liu Bo; Li Shihui;* Cui Dongmei;* “Chain Transfer to Toluene in Styrene Coordination Polymerization” Angew. Chem. Int. Ed. 2020, 59, 4324-4328.

5. Li Chuanyang; Wang Lingfang; Wang Meiyan; Liu Bo;* Liu Xinli;* Cui Dongmei;* “ Step-Growth Coordination Polymerization of 5-Hydroxymethyl Furfural with Dihydrosilanes: Synergistic Catalysis Using Heteroscopionate Zinc Hydride and B(C₆F₅)₃” Angew. Chem. Int. Ed. 2019, 58, 11434-11438.

6. Liu Bo, Wang Lingfang; Wu Chunji; Cui Dongmei;* “Sequence-controlled ethylene/styrene copolymerization catalyzed by scandium complexes” Polym. Chem. 2019, 10, 235-243.

7. Liu Bo, Qiao Kening, Fang Jian, Wang Tiantian; Wang Zichuan; Liu Dongtao; Xie Zhigang; Maron Laurent; Cui Dongmei; “Mechanism and Effect of Polar Styrenes on Scandium-Catalyzed Copolymerization with Ethylene” Angew. Chem. Int. Ed., 2018, 57, 14896-14901.

8. Liu Na; Liu Bo;* Cui Dongmei;* “Alkaline earth metal complexes stabilized by amidine and guanidine ligands: synthesis, structure and their catalytic activity towards polymerization of rac-lactide” Dalton. Trans. 2018, 47, 12623-12632.

9. Wu Chunji;^⊥Liu Bo;^⊥Lin Fei; Wang Meiyan; Cui Dongmei; “cis-1,4-Selective Copolymerization of Ethylene and Butadiene: A Compromise between Two Mechanisms” Angew. Chem. Int. Ed., 2017, 56, 6975-6979.

10. Lin Fei; Wang Meiyan; Pan Yupeng; Tang Tao; Cui Dongmei;* Liu Bo;* “Sequence and Regularity Controlled Coordination Copolymerization of Butadiene and Styrene: Strategy and Mechanism” Macromolecules, 2017, 50, 849-856.

11. Liu Bo; Cui Dongmei;* Tang Tao; “Stereo- and Temporally Controlled Coordination Polymerization Triggered by Alternating Addition of a Lewis Acid and Base” Angew. Chem. Int. Ed., 2016, 55, 11975-11978.

12. Liu Bo; Cui Dongmei; “Regioselective Chain Shuttling Polymerization of Isoprene: An Approach To Access New Materials from Single Monomer” Macromolecules, 2016, 49, 6226-6231.

13. Liu Na; Liu Bo; Yao Changguang; Cui Dongmei; “Immortal Ring-Opening Polymerization of rac-Lactide Using Polymeric Alcohol as Initiator to Prepare Graft Copolymer” Polymers, 2016, 8, DOI: 10.3390/polym8010017

14. Lin Fei; Wang Xingbao; Pan Yupeng; Wang Meiyan; Liu Bo;* Luo Yi;* Cui Dongmei;* “Nature of the Entire Range of Rare Earth Metal-Based Cationic Catalysts for Highly Active and Syndioselective Styrene Polymerization” ACS Catal. 2016, 6, 176-185.

15. Liu Na, Yao Changguang; Lin Fei; Liu Bo;* Cui Dongmei;* “An intensification and integration process of preparing thermal stable polylactide end-capped by phosphate ester” Polymer, 2015, 80, 104-108.

16. Liu Bo;^⊥ Wang Xingbao;^⊥ Pan Yupeng; Lin Fei; Wu Chunji; Qu Jingping; Luo Yi; Cui Dongmei; “Unprecedented 3,4-Isoprene and cis-1,4-Butadiene Copolymers with Controlled Sequence Distribution by Single Yttrium Cationic Species” Macromolecules, 2014, 47, 8524-8530.

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